Feeble metallicity and robust semiconducting regime in structurally sensitive Ba(Pb, Sn)O<sub>3</sub> alloys
نویسندگان
چکیده
Density functional calculations are carried out to study the symmetry and substitution-driven electronic phase transition in BaPb$_{1-x}$Sn$_x$O$_3$. Two end members BaSnO$_3$ BaPbO$_3$, found be insulating metallic, respectively. In latter case, metallicity arises with presence of an electron pocket, formed by Pb-s dominated conduction band edge, a hole pocket O-p valence bands. While carriers highly mobile, localized. Our reveals that can realized metallic cubic BaPbO$_3$ three ways order explore optoelectronic properties. Firstly, lowering lattice monoclinic through rotation tilting PbO$_6$ octahedra. Secondly, hydrostatic pressure, thirdly alloying Sn substitution. The soft phonon modes implies plausibility structural transitions. Furthermore, unlike earlier reports, we find substituted cannot exhibits topological insulator due absence inversion.
منابع مشابه
Monolayer semiconducting transition metal dichalcogenide alloys: Stability and band bowing
and band bowing Jun Kang, Sefaattin Tongay, Jingbo Li, and Junqiao Wu State Key Laboratory of Superlattices and Microstructures, Institute of Semiconductors, Chinese Academy of Sciences, P.O. Box 912, Beijing 100083, China Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA Department of Materials Science and Engineering, University of California,...
متن کاملNew azidotetrazoles: structurally interesting and extremely sensitive.
The treatment of triaminoguanidinium chloride with two equivalents of sodium nitrite under acidic conditions, followed by the cyclization with stoichiometric amounts of either sodium hydroxide solution or solid sodium carbonate yielded 1-amino-5-azidotetrazole (1), 5-azido-1-diazidocarbamoyltetrazole (2), and 1-(aminoazidocarbamoyl)-5-azidotetrazole (3). The three novel compounds could be isola...
متن کاملPolarization-sensitive optical phenomena in semiconducting and metallic nanowires
An analysis is presented of optical absorption and emission in semiconducting, metallic, and mixed coreshell nanowires are considered theoretically. Due to image forces caused by the difference in dielectric constants between nanowires and their environment, absorption and emission coefficients are different for light polarized parallel or perpendicular to the nanowire axis. As a result, the in...
متن کاملGardening and the Feeble-Minded
as the outdoor activities of mental defectives in institutions had previously been limited to elementary jobs, such as sweeping the paths, and generally acting as labourers to the staff engaged on the ornamental gardens. It was recognised that, for many years, patients in large mental institutions and colonies had been employed on farms, pig feeding, etc.; some of them had been taught to milk c...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Applied Physics Letters
سال: 2021
ISSN: ['1520-8842', '0003-6951', '1077-3118']
DOI: https://doi.org/10.1063/5.0061216